A Heterometallic σ-Silane Adduct from Cooperative Reactivity of an Iron–Aluminium Complex

Mark R. Crimmin

doi:10.1039/d5cc06456b

January 1, 2025Chemical CommunicationsOpen Access

A Heterometallic σ-Silane Adduct from Cooperative Reactivity of an Iron–Aluminium Complex

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Key Points

The protonation reaction produces a σ-silane complex from a heterometallic complex.
An alcohol is used for protonation, showcasing an effective and mild approach.
Cooperative reactivity was observed between the iron-aluminium complex leading to the adduct formation.
This finding highlights a new synthetic route without strong acids, enhancing reactivity understanding.

Implication

Protonation generates a σ-silane in an iron-aluminium complex, suggesting a new cooperative reactivity pathway.

Abstract

Protonation of a heterometallic silanide complex with an alcohol led to formation of a σ-silane complex. This reaction does not require a strong acid or weakly coordinating anion. Both metals...

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Cite This Study

Mark R. Crimmin (2025) studied this question.

synapsesocial.com/papers/6930dc8aea1aef094cca265a https://doi.org/10.1039/d5cc06456b

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A Heterometallic σ-Silane Adduct from Cooperative Reactivity of an Iron–Aluminium Complex

Key Points

Implication

Abstract

Discussion

Cite This Study

A Heterometallic σ-Silane Adduct from Cooperative Reactivity of an Iron–Aluminium Complex

Key Points

Implication

Abstract

Discussion

Cite This Study

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