Alumanyl Silanides as Multifunctional Reagents for Olefin Cycloaddition, CO Hydrosilylation, and Reductive CO Coupling

Moritz Ludwig; Johannes Voigland; Petra Vasko; Sebastian Stigler; Shigeyoshi Inoue

doi:10.1039/d5sc09910b

January 1, 2026Chemical ScienceOpen Access

Alumanyl Silanides as Multifunctional Reagents for Olefin Cycloaddition, CO Hydrosilylation, and Reductive CO Coupling

View Full Paper

Ask AI

Bookmark

Share

Key Points

Investigate the properties and potential applications of alumanyl silanides as reagents in various chemical reactions.
Implemented computational analysis to study alumanyl silanides' bonding characteristics.
Evaluated reactions involving olefin cycloaddition, CO hydrosilylation, and reductive CO coupling.
Identified the anionic Al-Si bond as a stabilizing factor in alumanyl silanides.
Demonstrated the presence of multiple-bond character in the alumanyl silanides.
Showed promising efficiency of alumanyl silanides in key chemical transformations.

Ask about this paper

Answers are grounded in this paper and cite their sources.

Implication

Computational analysis reveals alumanyl silanides' potential in chemical transformations, indicating their usefulness in synthetic chemistry.

Abstract

Alumanyl silanides represent a rare class of main group complexes, characterized by an anionic Al-Si bond, stabilized through an intimate ion pair. Computations revealed pronounced multiple-bond character in these alumanyl...

Discussion

No takes yet. Share an insight, caveat, or question.

Cite This Study

Ludwig et al. (2026) studied this question.

synapsesocial.com/papers/696b29a19396dd04f30d9856 https://doi.org/10.1039/d5sc09910b

View Full Paper

Ask AI

Bookmark

Share

Alumanyl Silanides as Multifunctional Reagents for Olefin Cycloaddition, CO Hydrosilylation, and Reductive CO Coupling

Key Points

Ask about this paper

Implication

Abstract

Discussion

Cite This Study

Alumanyl Silanides as Multifunctional Reagents for Olefin Cycloaddition, CO Hydrosilylation, and Reductive CO Coupling

Key Points

Ask about this paper

Implication

Abstract

Discussion

Cite This Study

Keep reading

Keep reading