Catalytic Dinitrogen Silylation by Tris(pyrazolyl)borate-Supported Titanium Complexes

Chenrui Liu; Ling-Ya Peng; Yumeng Chen; Jingyi An; Zhaoxin Li; Wenshuang Huang; Ganglong Cui; Hu Shaowei

doi:10.1039/d5cc04879f

January 1, 2025Chemical Communications

Catalytic Dinitrogen Silylation by Tris(pyrazolyl)borate-Supported Titanium Complexes

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Key Points

Catalysts facilitate N2 reduction, producing silylamines through a novel titanium complex.
The titanium silylimide serves as a well-defined model for this chemical transformation.
Observational analysis highlights the role of tris(pyrazolyl)borate ligands in the process.
This may enable advancements in nitrogen fixation techniques.

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Implication

Catalysts made from titanium and borate ligands demonstrate N2 silylation, suggesting new methods for nitrogen reduction.

Abstract

Titanium dinitrogen complexes supported by tris(pyrazolyl)borate and alkoxide/aryloxide ligands catalyse N 2 silylation. Titanium silylimide and disilylamide model complexes represent the first well-defined Group IV imide/amide catalysts for N 2 reduction. Silylamine...

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Liu et al. (2025) studied this question.

synapsesocial.com/papers/6930e8bdea1aef094cca3224 https://doi.org/10.1039/d5cc04879f

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Catalytic Dinitrogen Silylation by Tris(pyrazolyl)borate-Supported Titanium Complexes

Key Points

Ask about this paper

Implication

Abstract

Discussion

Cite This Study

Catalytic Dinitrogen Silylation by Tris(pyrazolyl)borate-Supported Titanium Complexes

Key Points

Ask about this paper

Implication

Abstract

Discussion

Cite This Study

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