Heterogenous Ni(OH)₂/NiOOH Redox Mediator on Bismuth Vanadate for Photoelectrochemical Oxidation of 5-Hydroxymethylfurfural

Yuming Zhang; Klaus Hellgardt

doi:10.1039/d5cy01024a

January 1, 2025Catalysis Science & Technology

Heterogenous Ni(OH)₂/NiOOH Redox Mediator on Bismuth Vanadate for Photoelectrochemical Oxidation of 5-Hydroxymethylfurfural

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Key Points

Photoelectrochemical oxidation of 5-hydroxymethylfurfural may enhance chemical production.
Results indicate biomass-derived 5-hydroxymethylfurfural can serve as an effective substrate.
Assessment using redox mediators with Bismuth Vanadate shows improved efficiency of the reaction.
Highlights the importance of alternative pathways for chemical synthesis from biomass.

Implication

Photoelectrochemical oxidation of 5-hydroxymethylfurfural reveals potential for biomass-derived chemical production.

Abstract

Replacing the kinetically demanding O2 evolution reaction (OER) in photoelectrochemical (PEC) water-splitting with the anodic oxidation of biomass-derived 5-hydroxymethylfurfural (HMF) to 2,5-furandicarboxylic acid (FDCA), a key building-block chemical for polymer...

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Cite This Study

Zhang et al. (2025) studied this question.

synapsesocial.com/papers/6932313d8e51979591dcedd8 https://doi.org/10.1039/d5cy01024a

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Heterogenous Ni(OH)₂/NiOOH Redox Mediator on Bismuth Vanadate for Photoelectrochemical Oxidation of 5-Hydroxymethylfurfural

Key Points

Implication

Abstract

Discussion

Cite This Study

Heterogenous Ni(OH)₂/NiOOH Redox Mediator on Bismuth Vanadate for Photoelectrochemical Oxidation of 5-Hydroxymethylfurfural

Key Points

Implication

Abstract

Discussion

Cite This Study

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