This analysis demonstrates how fluorinated compounds stabilize thallium(I) and silver(I) complexes, suggesting a new approach in chemistry.
Fluorinated and B-phenylated bis(pyrazolyl)borate and bis(pyridyl)borate ligands have been utilized in thallium(I) and silver(I)–ethylene chemistry. These ligands contain electron-withdrawing trifluoromethyl or pentafluorosulfanyl groups that create a chemically inert half-rim and,...
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Noonikara‐Poyil et al. (2025) studied this question.
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