Analysis reveals phonon transport enhances thermal conductivity in graphene, suggesting improved performance in thermoelectric devices.
Graphene’s extraordinary thermal conductivity makes it a compelling material for heat management in microelectronic circuits, lithium-ion batteries, and thermoelectric devices. In this article, we investigate its vibrational modes using a Born–von Karman model that includes first- and second-nearest-neighbor interactions. The resulting phonon dispersion relations agree well with experimental data, including acoustic flexural modes. To analyze phonon transport in mesoscopic graphene ribbons, we use both the Kubo–Greenwood and Landauer formalisms, as well as an independent channel method, which analytically maps zigzag-edged hexagonal ribbons into a set of single and dual chains via a unitary transformation. The resulting lattice thermal conductance spectra exhibit quantized steps that are smoothed in the presence of corrugations. We further explore the effects of temperature-induced rippling and buckling disorders on the phonon transport in graphene ribbons suspended over trenches. The predicted thermal conductance as a function of length and temperature closely matches experimental measurements, demonstrating the effectiveness of the independent channel method for the fully real-space modeling of corrugated graphene ribbons.
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Barreto et al. (2025) studied this question.
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