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December 11, 2025CrystEngComm2 citationsOpen Access

A Preformed 1‐D CuII2n Helical Chain as Precursor to a Decanuclear 0-D CuII8MnII2 Cluster: Synthesis, Structure and Magnetism

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KPKonstantinos N. PantelisDADimitris I. AlexandropoulosAEAlbert Escuer

Key Points

  • The research aims to explore the synthesis and properties of a helical chain and a decanuclear cluster.
  • Synthesis of a 1-D helical chain [CuII2(sacb)2(MeOH)]ₙ
  • Investigation of structural and magnetic properties.
  • Coordination chemistry of CuII and MnII with ligand N-salicylidene-2-amino-5-chlorobenzoic acid.
  • Successful synthesis of a decanuclear 0-D heterometallic CuII8MnII2 cluster.
  • Characterization of the magnetic properties of the synthesized structures.
  • Insights into the behavior of homometallic and heterometallic coordination complexes.

Abstract

The Schiff base ligand, N-salicylidene-2-amino-5-chlorobenzoic acid (sacbH2), was initially employed in both homometallic CuII and heterometallic MnII/CuII coordination chemistry. A 1-D helical chain, CuII2(sacb)2(MeOH)ₙ (1), and a decanuclear 0-D heterometallic...

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Cite This Study

Pantelis et al. (2025) studied this question.

synapsesocial.com/papers/694019342d562116f28f6d2dhttps://doi.org/10.1039/d5ce01110h
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