Effects of Ethanol Blends on Plug-In Hybrid Electric Vehicle Gaseous and Particulate Emissions Formation and Toxicity

This research investigates how blending ethanol with gasoline influences both gaseous and particulate emissions, as well as the toxicological characteristics of particulates emitted from a plug-in hybrid electric vehicle adapted to run on fuel mixtures containing up to 85% ethanol by volume. Testing was conducted on E10, E30, and E83 fuels, while the vehicle was exercised on a chassis dynamometer over three repetitions of the Federal Test Procedure and US06 cycles. Results showed important reductions in nitrogen oxide emissions for E30 and E83 for both cycles, along with reductions in particulate matter mass, black carbon, and solid particle number. Total hydrocarbon emissions demonstrated increases with E30 and E83 and tracked well with increases in benzene, toluene, ethylbenzene, and xylene isomers. Formaldehyde and acetaldehyde emissions trended in sympathy with higher-ethanol blending. The use of E30 and E83 blends produced more reactive emissions, which subsequently adversely affected the ozone-forming potential for these fuels compared to E10. The toxicological properties exhibited mixed results, with the higher-ethanol blends showing reduced oxidative stress compared to E10, while E83 induced a higher cytotoxic response relative to E30 and E10 fuels.