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December 8, 2025Inorganic Chemistry

Helical Chain Engineering in Chiral Metal–Organic Frameworks for Significantly Enhanced Circularly Polarized Luminescence

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Authors

AAAzhar AbbasHZHongrui ZhengZWZhao-xing Wang

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Overview

This research demonstrates enhanced circularly polarized photoluminescence in helical frameworks, suggesting new strategies for chiroptical systems.

Key Points

  • Helical framework dramatically improves circularly polarized photoluminescence, enhancing the luminescence dissymmetry factor.
  • A notable order-of-magnitude increase in luminescence dissymmetry factor was observed, reaching |g_lum| = 3.67 × 10-2.
  • Through synthesis of enantiomorphic CMOFs, a comparative study was performed focusing on structural differences.
  • Findings emphasize the role of helical engineering in developing advanced chiroptical materials.

Cite This Study

Abbas et al. (2025) studied this question.

synapsesocial.com/papers/694020e82d562116f28fabe1https://doi.org/10.1021/acs.inorgchem.5c05415
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