December 5, 2025Organic Letters

Photocatalytic Decarboxylative Hydroalkylation of Alkynes and Alkenes

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This method shows up to 88% yields of allylamine and arylpropylamine derivatives, indicating its efficiency for unsaturated hydrocarbons.

Allylamine and arylpropylamine derivatives were synthesized with up to 88% yields using this method.
The process employs organic 4CzIPN as a photocatalyst, avoiding the use of transition metals.
The mechanistic study indicated decarboxylation of amino acids generates alkyl radicals for reaction.
This approach highlights simple and mild conditions for the high-value-added transformation of hydrocarbons.

Lin et al. (2025) studied this question.

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