Asymmetric hydrogenation reveals up to 69% enantioselectivity in ketones under mild conditions, indicating manganese's catalytic potential.
Manganese complexes bearing ferrocenyl ligands with only planar chirality catalyse the hydrogenation of aromatic ketones under mild conditions: 30 °C, 30 bar H 2 , K 2 CO 3 , EtOH, down to 0.1 mol% manganese, with up to 69% ee.
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Yang et al. (2025) studied this question.
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