Critical review reports reaction rate constants for primary water radicals in aqueous solutions, establishing a benchmark database for radiation and redox chemistry.
Kinetic data for the radicals H⋅ and ⋅OH in aqueous solution,and the corresponding radical anions, ⋅O− and eaq−, have been critically pulse radiolysis, flash photolysis and other methods. Rate constants for over 3500 reaction are tabulated, including reaction with molecules, ions and other radicals derived from inorganic and organic solutes.
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Buxton et al. (1988) studied this question.
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