Magnetic filaments for fused deposition modeling, 3D printing, were produced by depositing polyamide 11 (PA11), by liquid–liquid phase separation and precipitation, onto exchange-coupled nanocomposite magnetic powders, SmCo5 + 20 wt% Fe produced by mechanical milling and subsequent annealing. The produced filaments have good mechanical properties, a tensile strength of 32 MPa and a maximum elongation of slightly over 40%. The filaments also present good magnetic properties: a high coercive field of 1 T at 300 K and nearly double the saturation magnetization and remanence, compared to filaments made by depositing PA11 on commercial SmCo5 and recycled SmCo5 powders and four times the energy product. This work shows that magnetic filaments made by encapsulating exchange-coupled magnetic nanocomposite powders in PA11 may be a viable option for the production of 3D-printed isotropic bonded magnets, as the high energy product and remanence especially can lead to a reduction in both magnetic powder quantity and rare earth elements required for high performance magnetic filaments. This in turn may reduce costs and improve sustainability.
Hirian et al. (Mon,) studied this question.