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January 6, 2026Chemical Communications3 citations

Iodine/iron oxide-catalysed aerobic oxidative coupling of phosphites and alcohols via in situ iodophosphate formation

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AFAlejandro FonsecaCMCarlos MárquezDVDirk De Vos

Key Points

  • The central aim is to achieve efficient synthesis of alkyl phosphates from H-phosphonates and alcohols.
  • Utilized iodine/iron oxide catalysts for the oxidative coupling process.
  • Performed reactions under aerobic conditions to facilitate iodophosphate formation.
  • Investigated yield outcomes of alkyl phosphates synthesized from H-phosphonates and alcohols.
  • Achieved moderate to high yields of alkyl phosphates.
  • Demonstrated the effectiveness of the oxidative coupling method.
  • Confirmed the role of in situ iodophosphate formation in the synthesis process.

Abstract

An efficient synthesis of alkyl phosphates from H-phosphonates and alcohols via in situ iodophosphate formation has been achieved in moderate to high yields.

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Cite This Study

Fonseca et al. (2026) studied this question.

synapsesocial.com/papers/695d8e503483e917927a5464https://doi.org/10.1039/d5cc05139h
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