What question did this study set out to answer?

To develop an artificial metalloenzyme for synthesizing specific nitrogen-containing compounds under eco-friendly conditions.

January 14, 2026Green Chemistry0 citationsOpen Access

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Cyclodesulfurization Reaction Catalyzed by Artificial Metalloenzymes Containing Cobalt Protoporphyrin IX Cofactors under Green Aqueous Solvent Conditions

XYXinjia YuJilin University YLYutong LiJilin University LWLei WangJilin University

Key Points

To develop an artificial metalloenzyme for synthesizing specific nitrogen-containing compounds under eco-friendly conditions.
Employed artificial Vitreoscilla hemoglobin as a catalyst
Conducted cyclodesulfurization reaction
Utilized cobalt protoporphyrin IX as a cofactor
Performed reactions in green aqueous solvent conditions
Successfully synthesized 3-amino-[1,2,4]-triazole
Resulting process is deemed environmentally friendly

Abstract

In this study, we report the development of an environmentally friendly artificial Vitreoscilla hemoglobin (VHb) for the synthesis of 3-amino-1,2,4-triazole and 4,3-apyridine. We employed a strategy that combines porphyrin substitution...

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Cyclodesulfurization Reaction Catalyzed by Artificial Metalloenzymes Containing Cobalt Protoporphyrin IX Cofactors under Green Aqueous Solvent Conditions

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Abstract

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