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Surface-mediated synthesis demonstrates new polymerization method using porphyrins, suggesting novel applications.
We report the surface-mediated synthesis of doubly-linked porphyrin polymers (DPPs) on Au(111) via thermally induced polymerization of 5,10,15,20-tetrakis[4-(1-methylethyl)phenyl]-21H,23H-porphine. The transformation proceeds through a hierarchical process involving (i) [3+3] cycloaromatization of...
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Chen et al. (2026) studied this question.
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