Supramolecular diiodo-chlorometalates(III) of Group 15 elements with halogen-substituted pyridiniums: an interplay of cation•••anion and I 2 •••halometalate halogen bonds

Nikita A. Korobeynikov; Andrey N. Usoltsev; Maksim Nailyevich Sokolov; Alexander S. Novikov; Sergey A. Adonin

doi:10.1039/d5ce01065a

January 1, 2026CrystEngComm

Supramolecular diiodo-chlorometalates(III) of Group 15 elements with halogen-substituted pyridiniums: an interplay of cation•••anion and I 2 •••halometalate halogen bonds

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Key Points

The study aims to explore the synthesis and halogen bonding characteristics of new hybrid polychloro-iodometallates.
Synthesis of four new hybrid polychloro-iodometallates.
Comparison of halogen bonding capabilities of Br atoms in specific compounds.
Halogen bond formation of Br atom in compounds 1 and 2 is prominently observed.
Synthesis confirmed unique interactions within the newly created hybrid metallates.

Implication

Hybrid polychloro-iodometallates were synthesized, highlighting halogen bond formation potential.

Abstract

Four new hybrid polychloro-iodometallates with halogen-substituted cations 4) were synthesized. The halogen bond formation ability of Br atom in 1 and 2 is prominent, which is confirmed by comparison of...

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Korobeynikov et al. (2026) studied this question.

synapsesocial.com/papers/696b2631d2a12237a934975e https://doi.org/10.1039/d5ce01065a

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Supramolecular diiodo-chlorometalates(III) of Group 15 elements with halogen-substituted pyridiniums: an interplay of cation•••anion and I 2 •••halometalate halogen bonds

Key Points

Implication

Abstract

Discussion

Cite This Study

Supramolecular diiodo-chlorometalates(III) of Group 15 elements with halogen-substituted pyridiniums: an interplay of cation•••anion and I 2 •••halometalate halogen bonds

Key Points

Implication

Abstract

Discussion

Cite This Study

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