Preferential Incorporation of Less Polarizable Donor Nitrogen in Porous Organic Polymers for Versatile Strategies

Key Points

• This research aims to evaluate how including less polarizable nitrogen in porous organic polymers can enhance material properties.
• Analyzed various porous organic polymers with differing nitrogen content.
• Examined the chelation capacity and Lewis basicity of these materials.
• Assessed their performance in acid-base coordination scenarios.
• Materials showed improved chelation capacity with less polarizable nitrogen.
• Greater stability in acid-base interactions was observed.
• The study suggests enhanced versatility in applications of these polymers.