As an effective technology for enhancing oil recovery, low-salinity water flooding requires further investigation into its microscopic displacement mechanisms and the regulatory roles of key ions. Based on microscopic visualization displacement experiments, this study systematically investigated the effects of injected water salinity, key ion types (Na+, K+, Ca2+, Mg2+, HCO3−, CO32−, SO42−, and OH−), and their concentrations on crude oil displacement behavior in both high- and low-permeability zones. Experimental results indicate that no significant correlation exists between displacement efficiency and injected water salinity in high-permeability zones. In low-permeability zones, displacement efficiency increases with decreasing salinity, peaking at 26.5% when injected water salinity reaches 5000 mg/L. The cation displacement efficiency in the formation, from highest to lowest, is Ca2+ > K+ > Mg2+ > Na+. The anion displacement efficiency, from highest to lowest, is OH− > SO42− > CO32− > HCO3−. When the CaCl2 concentration decreased from 100 wt% to 50 wt%, the displacement effect in the low-permeability zone improved further, indicating that a higher concentration of the divalent cation Ca2+ is not necessarily better. In medium-to-high salinity formation water reservoirs, and under conditions where the influence of clay minerals is disregarded, ion type and reservoir permeability are the most significant factors affecting oil recovery efficiency. These findings provide theoretical support for elucidating the micro-dynamic mechanisms of low-salinity water flooding in low-permeability zones and optimizing injection water formulations.
Liu et al. (Tue,) studied this question.