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January 22, 2026Organic & Biomolecular Chemistry0 citations

Remote-stereocontrolled (3+2)-annulation of pyrrolidinone-based MBH carbonates with 2-arylideneindane-1,3-diones

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RLRongzhen LiCZChangzhen ZhaiXCXuling Chen

Key Points

  • The aim is to explore a new enantioselective annulation method using MBH carbonates and arylideneindane diones.
  • Utilized a chiral phosphine catalyst
  • Conducted remote-controlled reactions
  • Performed under mild conditions
  • Successfully achieved enantioselective (3+2)-annulation
  • Constructed complex molecules efficiently

Abstract

With the assistance of a chiral phosphine catalyst, a remote-controlled enantioselective (3+2)-annulation between pyrrolidinone-based Morita-Baylis-Hillman (MBH) carbonates and 2-arylideneindane-1,3-diones has been successfully realized under mild conditions. This reaction efficiently constructs...

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Cite This Study

Li et al. (2025) studied this question.

synapsesocial.com/papers/6971bdcf642b1836717e2740https://doi.org/10.1039/d5ob01719j
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