Self-assembly of a high-nuclearity fullerene-like heteropolyoxometalate cage

Constructing fullerene-like metal-organic nanocage integrating novel architectures and unique functions remains a formidable challenge. Herein, an unprecedented high-nuclearity fullerene-like heteropolyoxometalate cluster, {Na32[(V V O2)30(Mo VI O4)12(PhPO3)48(CH3COO)12](CO3)2}•5MeCN (Mo24V30P48, MeCN=acetonitrile) was successfully...