Analysis reveals how bulky substituents influence molecular self-assembly in chalcogen-bonded networks.
The chalcogen-bonded [Ch⋯N] 2 synthons appeared in the crystal structures of newly synthesized coordination complexes of 2,1,3-chalcogenadiazoles with silver( i ) only when a bulky substituent was present at the C-4 position in the organic ligand.
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Alfuth et al. (2026) studied this question.
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