An efficient method demonstrates selective bond cleavage in tertiary amines, suggesting new synthesis pathways.
In this study, a metal-free and efficient method for the synthesis of sulflimines and sulfoximines via difluorocarbene enabled selective Csp3–N bond cleavage/S=N bond formation between tertiary amines and sulfenamide/sulfinamides has...
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Chen et al. (2026) studied this question.
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