Demonstrates efficient phosphorylation reactions in organic compounds, indicating potential for practical applications.
A practical and efficient regio- and stereoselective hydrophosphorylation of propiolates, as well as a multicomponent reaction incorporating an aldehyde component, is reported. Both processes proceed with atom economy in very straightforward experimental procedures. The reactions are catalyzed by DABCO (1,4-diazabicyclo[2.2.2]octane) and use readily available H-phosphonates as the phosphorylating agent.
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Delgado‐Hernández et al. (2026) studied this question.
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