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February 2, 2026Inorganic Chemistry Frontiers0 citations

Coligand-driven modulation of magnetic property in trigonal prismatic cobalt(II) single-ion magnets

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AZAoyun ZhangCZChennan ZhangJQJunnan Qiao

Key Points

  • The aim is to identify factors that influence magnetic anisotropy in cobalt(II) single-ion magnets.
  • Utilized a rigid tetradentate macrocyclic ligand
  • Focused on cobalt(II) ions arranged in trigonal prismatic geometry
  • Assessed magnetic properties through manipulation of ligand interactions
  • Identified key modifications that enhance magnetic anisotropy
  • Demonstrated improved performance of single-molecule magnets with specific ligand configurations

Abstract

Identifying the influencing factors and, consequently, manipulating the magnetic anisotropy are crucial for enhancing the performance of single-molecule magnets (SMMs). Using the rigid tetradentate macrocyclic host ligand 1,4,7,10-tetrabenzyl-1,4,7,10-tetraazacyclododecane (L), a...

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Cite This Study

Zhang et al. (2026) studied this question.

synapsesocial.com/papers/6980ff37c1c9540dea811fd8https://doi.org/10.1039/d5qi01722j
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