¹⁷ O NMR spectroscopy in polyoxometalate chemistry: advances, challenges, and applications in structure and catalysis

Thompson Izuagie; Daniel Lebbie

doi:10.1039/d5ra08401f

January 1, 2026RSC AdvancesOpen Access

¹⁷ O NMR spectroscopy in polyoxometalate chemistry: advances, challenges, and applications in structure and catalysis

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Key Points

This research aims to explore advancements in 17O NMR spectroscopy for understanding polyoxometalates.
Utilized high-field, MAS, and DNP-enhanced 17O NMR techniques.
Integrated NMR data with density functional theory (DFT).
Leveraged AI tools to analyze and interpret data.
Enabled site-resolved probing of oxygen in polyoxometalates.
Revealed new mechanistic insights into protonation and redox catalysis.
Showcased enhanced understanding of structural characteristics.

Implication

High-field NMR enhances understanding of structure and catalysis in polyoxometalates, suggesting new insights.

Abstract

Advances in high-field, MAS and DNP-enhanced 17 O NMR enable direct, site-resolved probing of oxygen in polyoxometalates. Integration with DFT and emerging AI tools reveals new mechanistic insight into structure, protonation and redox catalysis.

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Cite This Study

Izuagie et al. (2026) studied this question.

synapsesocial.com/papers/69843405f1d9ada3c1fb1b3e https://doi.org/10.1039/d5ra08401f

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¹⁷ O NMR spectroscopy in polyoxometalate chemistry: advances, challenges, and applications in structure and catalysis

Key Points

Implication

Abstract

Discussion

Cite This Study

¹⁷ O NMR spectroscopy in polyoxometalate chemistry: advances, challenges, and applications in structure and catalysis

Key Points

Implication

Abstract

Discussion

Cite This Study

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