Tracking the Environmental Impact of Mine Residues and Tailings in Sardinia (Italy) Using Imaging Spectroscopy

Italy is estimated to host thousands of abandoned mines, many of which contain large volumes of mine residues that negatively affect land and aquatic ecosystems, also posing a risk to human health. This study evaluates the effectiveness of spaceborne imaging spectroscopy combined with laboratory spectroscopy for characterizing the mineralogy and geochemistry of residues from the abandoned Montevecchio sulfide mine in southwestern Sardinia, a site recognized as a significant source of environmental pollution. Mine tailings and their downstream dispersion along the Rio Irvi River were systematically studied and sampled in the field. Collected samples were analyzed in the lab using an Analytical Spectral Device (ASD) spectroradiometer, complemented by powder X-ray Diffraction (XRD) for mineralogical characterization. Affected zones were subsequently mapped using the Environmental Mapping and Analysis Program (EnMAP) hyperspectral satellite data at a 30 m spatial resolution, by applying a polynomial fitting technique to the image spectra. The results reveal the presence of Fe- and Zn-bearing sulfates and oxy/hydroxides, indicative of acidic-to-circum-neutral drainage conditions in the mine tailings and along affected streams. Specifically, EnMAP was able to detect jarosite and subtle chemical and physical variations in Fe-hydroxides. This integrated approach enabled the delineation of environmental conditions and zones with varying acidity based on the spectral characteristics of secondary minerals. Overall, the study demonstrates the potential of EnMAP data for mapping acid mine drainage and assessing environmental impacts in legacy mining areas.