New germylenes perform N-formylation of amines using CO2, suggesting a key role for the pyrazole ligand.
New germylenes supported by an anilido-pyrazole ligand for the catalytic N -formylation of amines using CO 2 and hydrosilanes is reported. The reaction mechanism suggests an important role of the hemilabile pyrazole ligand in the present protocol.
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Pandey et al. (2026) studied this question.
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