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February 6, 2026Magnetochemistry0 citationsOpen Access

Ligand-Induced Self-Assembly of Metal Clusters for Magnetic Applications

Ligand-Induced Self-Assembly of Clusters by Pyridine–Amine–Carboxylate Frameworks of 3d Transition Metals: Structural and Magnetic Aspects

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Authors

ARAmit RajputAAAkram AliHAHimanshu Arora

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Overview

This review demonstrates the construction of magnetic metal clusters using ligand self-assembly, suggesting new avenues for functional materials.

Key Points

  • The aim is to explore how ligand-driven self-assembly influences the structure and magnetic properties of metal clusters.
  • Review of coordination-driven self-assembly processes
  • Analysis of multidentate ligands and their role in cluster formation
  • Examination of various metal cluster geometries and topologies
  • Assessment of magnetic characteristics related to different frameworks
  • Ligand-assembled clusters exhibit diverse geometries, including icosahedral and cubane-type motifs.
  • Clusters generally possess high symmetry and robust structures.
  • Many clusters show high spin ground states and slow magnetization relaxation.
  • Magnetic behavior is influenced by metal ion types, ligand bridging, and coordination environments.

Cite This Study

Rajput et al. (2026) studied this question.

synapsesocial.com/papers/698585db8f7c464f23009907https://doi.org/10.3390/magnetochemistry12020022
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