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The research aims to improve the stability and utility of metal-organic frameworks for solvent detection.

Hetero-nuclear metal organic framework with enhanced hydrolytic stability for distinguishing between the protic and aprotic solvents and detecting water in organic solvents

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The research aims to improve the stability and utility of metal-organic frameworks for solvent detection.
Synthesize a hetero-bimetallic metal-organic framework (Zn-Cd-MOF) via a solvothermal approach.
Characterize the fluorescence properties of the framework for distinguishing solvent types.
Assess the stability and reusability of the framework in detecting water in organic solvents.
Zn-Cd-MOF displays enhanced stability in water and organic solvents compared to its monometallic counterparts.
Demonstrates tunable fluorescence properties via excited-state intramolecular proton transfer.
Maintains structural integrity and stable performance over multiple detection cycles for at least 5 cycles.

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Metal-organic framework distinguishes protic from aprotic solvents, highlighting its stability and reusability in organic solvent detection.

Xu et al. (2026) studied this question.

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Metal-organic framework distinguishes protic from aprotic solvents, highlighting its stability and reusability in organic solvent detection.