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February 8, 2026Journal of the American Chemical Society

Chemoselective 1,2-Sulfonamidoazidation of Styrene via Single-Atom-Site Cobalt Catalysis

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Authors

WXWenxuan XueHuazhong University of Science and TechnologyJJJing JiaHuazhong University of Science and TechnologyMWMingtao WuTongji University

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Implication

Heterogeneous catalyst enables selective reaction in alkenes, suggesting better methods for organic synthesis.

Key Points

  • This work aims to improve chemo- and regioselectivity in the functionalization of styrenes using a cobalt catalyst.
  • Utilized a heterogeneous cobalt single-atom-site catalyst.
  • Focused on the 1,2-sulfonamidoazidation of styrenes.
  • Assessed functional group tolerance and catalyst recyclability.
  • Achieved high selectivity in styrene functionalization.
  • Demonstrated excellent recyclability of the cobalt catalyst.
  • Showed good tolerance for various functional groups.

Cite This Study

Xue et al. (2026) studied this question.

synapsesocial.com/papers/698828eb0fc35cd7a8848cbdhttps://doi.org/10.1021/jacs.5c12264
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