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February 9, 20260 citationsOpen Access

Biomass-Derived Polysilsesquioxane Nanofilament Reinforced Porous Aerogel for Durable Passive Radiative Cooling across All Day and Weather Conditions

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JXJie XuKCKangwei ChenAMAlessandro Maturilli

Key Points

  • The aim is to enhance passive radiative cooling by utilizing polysilsesquioxane nanofilaments in biomass-derived aerogels.
  • Developed a three-dimensional framework using one-dimensional polysilsesquioxane nanofilaments in biomass-derived aerogels.
  • Conducted thermal tests to measure sunlight reflection, thermal emission, and cooling power.
  • Evaluated aerogel properties such as thermal stability, conductivity, superhydrophobicity, and density.
  • Achieved over 97% sunlight reflection and thermal emission in the 8-13 μm range.
  • Demonstrated a cooling power of 138.6 W m over 720 hours, reducing ambient temperatures by 9 °C.
  • Confirmed thermal stability, low thermal conductivity of 29.0 mW m K, and superhydrophobicity with contact angle ∼175°.

Abstract

Passive radiative cooling (PRC) is a potentially sustainable strategy by reflecting sunlight (0.3-2.5 μm) and emitting heat through the atmospheric window (8-13 μm) without energy consumption. However, challenges remain due to high sunlight irradiance (1000 W m) during the day. Our research addresses these challenges by incorporating one-dimensional polysilsesquioxane nanofilaments (1D PSNFs) into micro- and nanoporous biomass-derived aerogels, forming a three-dimensional framework. The designed sustainable aerogel cooler achieves greater than 97% sunlight reflection and thermal emission, resulting in a cooling power of 138.6 W m over 720 h, reducing ambient temperatures by 9 °C. In addition, the aerogel cooler demonstrates high thermal stability, low thermal conductivity (29.0 mW m K), superhydrophobicity (water contact angle ∼175°), low density (44.43 kg/m), and a large surface area (137.84 m/g). These features enable effective radiative cooling across various weather conditions, while also maintaining environmental sustainability.

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Cite This Study

Xu et al. (2025) studied this question.

synapsesocial.com/papers/698979e9f0ec2af6756e7f83https://doi.org/10.5167/uzh-291042
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