PulseExploreJournal ClubDebatesTrendingResearchersJournals
Instagram
HomeExploreJournal ClubTrending
Synapse
⌘+K
Synapse
February 11, 2026New Journal of Chemistry0 citations

Pd II and Pt II complexes bearing acetamide and thioacetamide functionalized heteroscorpionates and their application in the hydrosilylation of terminal alkynes

View Full Paper
MOMariana Ortiz-HernándezVMVictor Ivan Iván Noguez MaldonadoVSVerónica Salazar

Key Points

  • The research aims to synthesize and characterize Pd II and Pt II complexes for their use in hydrosilylation reactions.
  • Synthesis of cationic complexes using N-phenyl-2,2-bis(3,5-dimethylpyrazol-1-yl)thioacetamide as a ligand.
  • Reaction with MCl2 (where M = Pd, Pt) in acetonitrile.
  • Characterization of the synthesized complexes to confirm their structure.
  • Successful formation of cationic complexes [(pbptamH)2M]Cl2 with M being Pd or Pt.
  • Potential effectiveness of these complexes in catalyzing hydrosilylation of terminal alkynes.

Abstract

Reaction of ligand N-phenyl-2,2-bis(3,5-dimethylpyrazol-1-yl)thioacetamide (pbptamH) with MCl2 (M = Pd, Pt) in acetonitrile, results in the formation of the cationic complexes 1a-b with the general formula (pbptamH)2MCl2. If the former...

Ask AI
Helpful
Bookmark
Share
View Full Paper

Cite This Study

Ortiz-Hernández et al. (2026) studied this question.

synapsesocial.com/papers/698c1cb3267fb587c655f4c1https://doi.org/10.1039/d5nj04709a
Ask AI
Helpful
Bookmark
Share
View Full Paper

Also Consider

Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context:

  1. 1Models of the active sites of zinc-containing enzymes: the structure of acetato[hydrotris(3-tert-butyl-5-methylpyrazol-1-yl)borato]zinc(II)1996 · 9 citations
  2. 2Controlled Access to Four- and Six-Membered Palladacycles via Modifying Donor Abilities of β-Ketiminato Ligands (“NacAcs”)2022 · 12 citations
  3. 3OLEX2 : a complete structure solution, refinement and analysis program2009 · 32,429 citations
  4. 4Cross‐Electrophile C(sp 2 )−Si Coupling of Vinyl Chlorosilanes2020 · 129 citations
  5. 5CCDC 2513066: Experimental Crystal Structure Determination2026 · 1 citations