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February 12, 2026Advanced ScienceOpen Access

Ambient Hydrocarbonylation of Olefins Enabled by Visible‐Light

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Authors

HLHongchi LiuTZTianze ZhangHHHanmin Huang

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Overview

Photocatalytic process enables efficient ambient hydrocarbonylation of olefins, suggesting a safer alternative to conventional methods.

Key Points

  • The research aims to develop a safe and efficient method for the hydrocarbonylation of olefins at ambient conditions.
  • Developed a photocatalytic approach using visible light irradiation.
  • Utilized a palladium-catalyzed process for olefin hydrocarbonylation.
  • Explored various reactions including hydroformylation and hydroaminocarbonylation.
  • Successfully achieved hydrocarbonylation under ambient conditions (room temperature, 1 atm CO).
  • Demonstrated excellent regioselectivity for carboxylic acids, esters, and aldehydes.
  • Mechanistic studies indicated concurrent olefin and CO insertion through the carbonyl palladium iodide complex.

Cite This Study

Liu et al. (2026) studied this question.

synapsesocial.com/papers/698d6e2a5be6419ac0d539f1https://doi.org/10.1002/advs.74323
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