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February 12, 2026Dalton Transactions0 citations

Sulfur Insertion into Group 12 Metal Dithiolate Complexes: Metal-Dependent Equilibria

MSMuhammad SohailCHCarsten HeinsenAOAllen Grayson Oliver

Key Points

  • The study aims to explore the structural relationships and equilibria in metal dithiolate complexes of Cd and Hg.
  • Synthesis of dianionic bis(carboxamide)pyridine-supported metal(II) dithiolate complexes.
  • Comparison of isostructural coordination with a zinc variant.
  • Evaluation of the effects of ionic radius on coordination geometry.
  • Cd2+ and Hg2+ complexes exhibited isostructural coordination to the zinc complex.
  • Notable geometric distortion occurred due to the differences in ionic radii between metals.
  • Different structural characteristics were observed in the three metal complexes.

Abstract

Dianionic bis(carboxamide)pyridine-supported metal(II) dithiolate complexes of Cd 2+ and Hg 2+ showed isostructural N 3 S 2 coordination to a previously reported zinc variant, but changes in ionic radius resulted in distortion of the coordination...

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Cite This Study

Sohail et al. (2026) studied this question.

synapsesocial.com/papers/698d6f0d5be6419ac0d55148https://doi.org/10.1039/d6dt00074f
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