Synthesis, structural and Anti-Bacterial Study of Mn(II), Co(II), Zn(II), and Hg(II) Complexes with New Ligand 4-nitro-N-(pyrimidin-2-ylcarbamothioyl) benzamide

Using a 2-Amino pyrimidine and 4-nitrobenzoyl isothiocyanate , a novel ligand 4-nitro-N - (pyrimidin-2-ylcarbamothioyl) benzamide (L') has been created. A few of the ligand's transition metal complexes have been designed and described using the UV-vis spectra, FT-IR, magnetic susceptibilities, conductivity measurements, and atomic absorptions. The ligand was identified using C.H.N.S., UV-Vis, FT-IR, and 1 H, 13 CNMR spectra. The behavior of the ligand is comparable to that of a bidentate coordinating through atoms S and O. According to the data, the chemical formula of every complex created was [M(L)2Cl2] (M (II) = Mn, Co, Zn and Hg). An octahedral geometrical structure was proposed for each complex. Escherichia coli and Staphylococcus aureus are two microorganisms that the metal and ligand complexes show good activity against.