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February 14, 2026Sensor Review0 citations

Impedimetric detection of an endocrine disruptor (bisphenol A) based on an organophosphorus compound (TBP) as a receptor

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SLSelma LaguelMSMohamed Elhadi Samar

Key Points

  • The study aims to detect the endocrine disruptor bisphenol A (BPA) in aqueous solutions using an impedimetric sensor.
  • Developed a sensor using a polymeric membrane and ion-sensitive silica electrode.
  • Incorporated tributyl-phosphate as an ionophore in the sensor preparation.
  • Evaluated sensor characteristics such as sensitivity and selectivity through impedance spectroscopy.
  • Achieved significant linearity of detection in the range from 10–3 to 10–10 ppm.
  • Demonstrated a correlation coefficient of 0.974 and a detection limit of around 10–11 ppm.
  • Indicated the sensor's sensitivity, reproducibility, and long-term stability for detecting BPA.

Abstract

Purpose The purpose of this paper is to study the detection of an endocrine disruptor bisphenol A (BPA), present in aqueous solution by electrochemical impedance spectroscopy. Design/methodology/approach A polymeric membrane and an ion-sensitive electrode (a silica electrode) are spatially coupled to form the current sensor. The preparation of the polymeric membrane involves the incorporation of an ionophore (TBP), a polymer based on siloprene K1000 and a plasticizer based on siloprene crosslinking K11. Characterization, sensibility and the selectivity of this sensor have been evaluated by impedance spectroscopy. Findings A layer of tributyl-phosphate deposited on silica electrode has been characterized by impedance spectroscopy method. Under the optimal experimental conditions, a number of significant factors were optimized. The method exhibited good linearity in the range of 10–3 to 10–10 ppm with a good correlation coefficient of 0.974 and the detection limit is around 10–11 ppm, indicating the sensitivity, reproducibility and long-term stability of the sensor overlooked the target element. Practical implications The practical implication of electrochemical sensors lies to their ability to provide rapid, sensitive and cost-effective detection of BPA in food safety monitoring, environmental surveillance and public health protection. Originality/value The result of this study demonstrate that the proposed sensor offers a convenient and reproducible method. It shows strong potential to rival conventional analytical techniques, particularly in terms of speed, stability and economic feasibility.

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Cite This Study

Laguel et al. (2026) studied this question.

synapsesocial.com/papers/699011932ccff479cfe58628https://doi.org/10.1108/sr-08-2025-0586
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