Synthesis and photophysical properties of bis-NHC platinum(II) complexes bearing bipyridine ligands furnished with two anionic closo-monocarborane clusters [CB11H12]−

Haibo Yao; Ling Pei; Yuzhen Zhang; Yunjun Shen

doi:10.1039/d5tc04159g

January 1, 2026Journal of Materials Chemistry C

Synthesis and photophysical properties of bis-NHC platinum(II) complexes bearing bipyridine ligands furnished with two anionic closo-monocarborane clusters [CB11H12]−

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Key Points

To investigate the synthesis and properties of bis-NHC platinum(II) complexes with bipyridine ligands containing carborane clusters.
Synthesis of four Pt(II) complexes using bis-NHC ligands and cyclometalated bipyridine ligands.
Incorporation of two monoanionic closo-monocarborane clusters into the complexes.
Documented synthesis of four distinct platinum(II) complexes.
Characterized the photophysical properties of the synthesized complexes.

Implication

Synthesis reveals photophysical properties of platinum(II) complexes with bipyridine, suggesting potential applications in materials science.

Abstract

Four Pt(II) complexes have been synthesized by utilizing the primary ligand of bis-NHC (dpdb, dpdi) and featuring cyclometalated ligands of bipyridine (bpy) decorated with two monoanionic closo-monocarborane clusters. All four...

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Cite This Study

Yao et al. (2026) studied this question.

synapsesocial.com/papers/69926552eb1f82dc367a13fc https://doi.org/10.1039/d5tc04159g

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Synthesis and photophysical properties of bis-NHC platinum(II) complexes bearing bipyridine ligands furnished with two anionic closo-monocarborane clusters [CB11H12]−

Key Points

Implication

Abstract

Discussion

Cite This Study

Synthesis and photophysical properties of bis-NHC platinum(II) complexes bearing bipyridine ligands furnished with two anionic closo-monocarborane clusters [CB11H12]−

Key Points

Implication

Abstract

Discussion

Cite This Study

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