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Demonstrates a dual iron/nickel photocatalytic strategy for selective C-H sulfoxidation in alkanes, suggesting a practical method for sulfur-containing compounds.
Sulfoxides occupy a central role in natural products and bioactive molecules, yet their direct construction from simple feedstocks remains challenging. Herein, we report a dual iron/nickel photocatalytic strategy for the selective C(sp³)-H sulfoxidation of liquid/gaseous alkanes using industrially abundant aryl sulfonyl chlorides. Broad substrate scope, good functional group tolerance, operational simplicity, high chemoselectivity, scale-up synthesis, and late-stage modification are demonstrated, providing a practical platform for the preparation of high-value sulfur-containing compounds.
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Wang et al. (2026) studied this question.
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