Demonstrates a solvent-controlled method to synthesize difluoroalkylated cyclopentanes from terminal alkynes, suggesting a new synthetic strategy.
The 1,1,2-trifunctionalization of alkynes is an atom-economical strategy that enables the rapid construction of multiple C–C and C–heteroatom bonds in a single synthetic operation. Herein, we present a radical addition-translocation-cyclization...
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Han et al. (2026) studied this question.
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