Guanidinato-zinc complexes demonstrate effective synthesis of cyclic carbonates and oxazolidinones, suggesting a new pathway for these compounds.
Guanidinato-stabilized zinc complexes, featuring or lacking additional functionalities, were synthesized through the reaction between guanidine derivatives, specifically (iPrHN)₂CNR (R = Ph, 2-FC₆H₄, 2-Ph₂PC₆H₄, 2-PhSC₆H₄), and ZnMe₂. The simple complex [ZnMe{(iPrN)(iPrNH)CNPh}]...
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Gómez et al. (2026) studied this question.
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