Electro-Optical Properties of Excitons in CdSe Nanoplatelets

Applying a constant external electric field to a semiconductor nanostructure with Wannier–Mott excitons, in which the electron and hole interact via a centrally symmetric Coulomb potential, alters the symmetry of the system. When the electric field is applied parallel to the z-axis, the system exhibits cylindrical symmetry; when the field lies in the x−y plane, the symmetry is broken. These symmetry changes affect the optical properties of the system. We present a theoretical calculation that yields analytical expressions for the optical functions of CdSe Nanoplatelets—reflectivity, transmissivity, and the absorption coefficient—in an external homogeneous electric field. From these, we focus on the absorption coefficient. We consider various configurations, with the external field oriented perpendicular and parallel to the platelet planes. Using the real density matrix approach, we calculate the linear electro-optical functions of CdSe nanoplatelets, taking into account the effect of dielectric confinement on excitonic states. We also discuss the impact of platelet geometry (thickness and lateral dimensions) and applied field strength on the spectrum.