Demonstrates new coordination compounds formed with silver nitrate and amide ligands, suggesting key structural insights.
Complex formation of AgNO with L, L = urea (Ur), N,N'-dimethylurea (DMUr) and acetamide (AA) in aqueous solution is studied. Three new coordination polymers, [Ag(AA)(μ-NO)](I), [Ag(μ-DMUr)(μ-NO)](II) and [Ag(μ-Ur-ON)(μ-NO)](III) are isolated and structurally characterized. Silver coordination surrounding is described with the DFT and QTAIM methods. Bond strength and features of Ag(I) interaction with L and nitrate ligands are estimated. Thermal properties of I–III are studied. On the basis of the TGA data, a probable mechanism of thermal destruction is suggested.
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R. A. Rodriguez Pineda (2025) studied this question.
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