A new dioxo-molybdenum complex derived from an amide-based imine derivative for the fluorescence recognition of Zr( iv ) with phosphatase activity
Key Points
The research aims to develop a new dioxo-molybdenum complex for the selective recognition of zirconium ions and its effect on phosphatase activity.
Synthesis of an amide-imine based molybdenum complex (DBASL)
Evaluation of fluorescence emission in response to zirconium ions
Assessment of catalytic activity on the hydrolysis of phospho-ester bonds
The DBASL complex shows selective fluorescence emission for zirconium ions at a limit of detection of 23.1 nM.
DBASL efficiently catalyzes the hydrolysis of the phospho-ester bond in p-NPP, indicating phosphatase activity.
Abstract
An amide-imine (DBASL)-based Mo( vi ) complex selectively recognizes ZrO 2+ via sky-blue emission having LOD of 23.1 nM. The DBASLM efficiently catalyses the hydrolysis of the phospho-ester bond in p -NPP.
A new dioxo-molybdenum complex derived from an amide-based imine derivative for the fluorescence recognition of Zr( iv ) with phosphatase activity | Synapse