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Research uncovers a novel method to synthesize heteroaryl-C-Δ1,2-glycosides, suggesting broad potential applications.
This work reports an unprecedented and efficient approach for the synthesis of a diverse range of heteroaryl-C-Δ¹,²-glycosides via N-heterocyclic carbene (NHC)-catalyzed E1cB elimination. The method provides a highly practical, scalable, and broadly applicable strategy, delivering excellent yields across various substrates. Importantly, under the optimized conditions, numerous sensitive functional and protecting groups in the heteroaryl-C-Δ¹,²-glycosides remained intact.
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Hu et al. (2026) studied this question.
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