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March 4, 2026Nature Communications2 citationsOpen Access

Extreme longitudinal thermal conductivity and non-diffusive heat transport in isotopic hBN

CBCléophanie Brochard-RichardGBGaia Di BerardinoÉHÉtienne Herth

Key Points

  • The research aims to measure and analyze the thermal conductivity of monoisotopic hexagonal boron nitride at various temperatures.
  • Utilized suspended microbridge technique for direct measurement.
  • Employed Raman spectroscopy to map temperature profiles.
  • Refined models with increased data points to enhance accuracy.
  • Investigated thermal transport deviation from classical diffusion regimes.
  • Measured thermal conductivity values exceeded 1650 W.m−1.K−1 at room temperature.
  • Temperature profiles were linear above 300 K and non-linear below this temperature.
  • Findings indicate significant non-diffusive heat transport in 2D materials.
  • The study suggests a need for a new theory to explain heat transport phenomena.

Abstract

Abstract We measure the temperature profile and investigate the thermal conductivity of suspended monoisotopic hexagonal boron nitride (h 10 BN) heterostructures by combining suspended microbridge technique and Raman spectroscopy. The thermal conductivities exceed 1650 W.m −1 .K −1 at room temperature, significantly higher than in previous reports, highlighting the crucial influence of the measurement conditions on the experimental results. By including more data points, we refine our models beyond the accuracy of conventional approaches. Our results show a striking deviation of thermal transport from the classical diffusion regime described by Fourier’s law: while the temperature profiles are linear above 300 K, they become clearly nonlinear below this temperature, indicating a strong non-diffusive heat transport regime. This behavior underscores the need for a new theoretical framework to fully account for heat transport in two-dimensional materials. Ultimately, our findings pave the way for innovative heat dissipation technologies and challenge conventional paradigms in nano-heat engineering. This study establishes a practical framework linking Raman-based temperature mapping, the number of measurement points, and thermal simulations to reliably determine the in-plane thermal conductivity of 2D materials.

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Cite This Study

Brochard-Richard et al. (2026) studied this question.

synapsesocial.com/papers/69a7cd8cd48f933b5eed9fb8https://doi.org/10.1038/s41467-026-69907-x
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