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Measurements show a high temperature coefficient of resistivity in hydrogen-loaded palladium, suggesting new phase transitions.
As reported in previous papers, we performed many electrolytic loading tests using thin Pd wires, achieving loading ratios of H/Pd ≥ 0.95 (H/Pd over-loading). In particular, we defined a reproducible "loading protocol" suitable for achieving such an over-loading level, based on the use of very diluted acid electrolytic solutions (with additions of tenths of micro-moles of Ca or Sr or Li cations and some hundred nano-moles of Hg ions) and operating with electrolytic current cycles from a few mA up to one hundred mA. By observing the day/night cyclic fluctuations of electrical resistance, as a function of the corresponding temperature variations, of stable, long term, H/Pd loadings we were able to calculate the temperature coefficient of resistivity (K_0) of the Pd-H system at very high H/Pd loadings. Many years ago (on 1998) we reported an unexpected value showing that the K_0 parameter values increase when H/Pd exceeds 0.75 (i.e. after that R/Ro goes beyond the 1.8 peak value, i.e. to the right side of the R/Ro / H/Pd curve). This fact was confirmed by the ISR-Stanford Group (McKubre and Tripodi) and Pirelli-Research Group (Gamberale and Garbelli). In this paper we show several measurements of K_0 at different overloading values of H/Pd up to ≅ 1 (corresponding at R/Ro=1.12) where K_0 =(13±1) * 10^-3 K^-1 , i.e. more than six times higher than the minimum value achieved at the R/Ro=1.8 peak value. This result can corroborate the hypothesis that a new Pd-H phase (full β-phase or the beginning of β+α phase) could occur after the H/Pd=0.75 loading ratio (at the end of β+α phase), as claimed by many authors as the necessary condition for excess (anomalous) heat from Pd-D system (at D/Pd ≥ 1).
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Francesco et al. (2006) studied this question.
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