What question did this study set out to answer?

To synthesize and investigate the structural and photophysical properties of two isostructural coordination polymers.

March 6, 2026Journal of Materials Chemistry C0 citations

Intrinsic Fluorescence–Spin Crossover Synergy in a 3D Fe(II) Hofmann-Type Framework Built from 1,6-dipyridylpyrene and MI(CN)₂⁻ (MI = Ag, Au) bridging ligands

AOAlejandro Orellana‐SillaUniversitat de València CBCarlos Bartual‐MurguiUniversitat de València GMGábor MolnárCentre National de la Recherche Scientifique

Key Points

To synthesize and investigate the structural and photophysical properties of two isostructural coordination polymers.
Synthesis of coordination polymers using 1,6-dipyridylpyrene and MI(CN)₂ bridging ligands
Structural characterization through appropriate techniques
Photophysical investigations to assess fluorescence and spin crossover behavior.
Successfully synthesized two isostructural Hofmann-type frameworks with distinct metal centers (Ag and Au)
Observed intrinsic fluorescence linked to the molecular structure
Identified spin crossover phenomena in the polymeric framework.

Abstract

We report the synthesis, structural characterization, and photophysical investigation of two isostructural 3D Hofmann-type coordination polymers, FeII (1, 6-dipypyr) MI (CN) 22) · (toluene) (1, 6-dipypyr = 1, 6-dipyridylpyrene, MI = Ag (1Ag), Au (1Au) ), incorporating a pyrene based. . .

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Cite This Study

Orellana‐Silla et al. (Thu,) studied this question.

synapsesocial.com/papers/69aa70d6531e4c4a9ff5af4d https://doi.org/https://doi.org/10.1039/d6tc00153j

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