Demonstrates stable radical-mediated living polymerization in poly(methyl methacrylate), suggesting potential applications in advanced materials.
Poly(methyl methacrylate)s with side-chain and terminal TEMPO (2,2,6,6-tetramethyl-l-piperidinyl-1-oxy) units were prepared by irradiating corresponding benzoin-containing polymers at λ = 350 nm in the presence of TEMPO. Application of these polymers in stable-radical-mediated living polymerization caused degradation of precursor polymers.
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Düz et al. (1998) studied this question.
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