Polymeric salts initiate cationic polymerization in cyclohexene oxide, suggesting new synthesis methods.
Polymeric allyl pyridinium salts were synthesized from styrene and 4-vinyl pyridine copolymers by quaternization and counteranion exchange reactions. The initiation capability of these copolymers, in conjunction with a photochemical free radical source such as benzoin, via an addition –fragmentation mechanism in the cationic polymerization of cyclohexene oxide is investigated.
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Onciu et al. (2001) studied this question.
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